You have a statutory right to take 52 weeks of adoption leave if you:
The right to take adoption leave is a right from day one of your employment (although 26 weeks’ service is needed to claim Statutory Adoption Pay).
Only one adopting parent (the 'primary adopter') can take statutory adoption leave. However, some of the leave (up to 50 weeks) can be shared between you, as Shared Parental Leave, as long as both parents qualify.
If you are both employees, you choose between yourselves who is going to be the 'primary adopter' for the purposes of exercising your employment rights.
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